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The Lead Tetra-acetate Oxidations of Some N-Arylaminofumarates in the Presence of Trifluoroacetic Acid

Mohd Aspollah Sukari

Pertanika Journal of Tropical Agricultural Science, Volume 8, Issue 3, December 1985

Keywords: Lead tetra-acetate; oxidative cleavage

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p-Chloroanilino-, p-acetylanilino-and p-toluidino-fumarates are oxidized by lead tetraacetate in low yields to give oxanilate. Similar oxidation of p-acetylanilinofumarate in the presence of trifluoroacetic acid affords only oxanilate. p-Toluidino and p-chloroanilino-fumarates with lead tetra acetate/ trifluoroacetic acid give mixtures of oxazin, azobenzene and anilide.

ISSN 1511-3701

e-ISSN 2231-8542

Article ID

PERT-0315-1985

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